$userdb=Array
(
(0) => Array
    (
        (uid) => '100',
        (name) => 'Sandra Shush',
        (url) => 'urlof100'
    ),

(1) => Array
    (
        (uid) => '5465',
        (name) => 'Stefanie Mcmohn',
        (pic_square) => 'urlof100'
    ),

(2) => Array
    (
        (uid) => '40489',
        (name) => 'Michael',
        (pic_square) => 'urlof40489'
    )
);

$key = array_search(40489, array_column($userdb, 'uid'));