def recursive_items(dictionary):
    for key, value in dictionary.items():
        if type(value) is dict:
            yield from recursive_items(value)
        else:
            yield (key, value)

a = {'a': {1: {1: 2, 3: 4}, 2: {5: 6}}}

for key, value in recursive_items(a):
    print(key, value)