$ch = curl_init();
curl_setopt($ch, CURLOPT_RETURNTRANSFER, 1);
curl_setopt($ch, CURLOPT_HEADER, 1);
// ...

$response = curl_exec($ch);

// Then, after your curl_exec call:
$header_size = curl_getinfo($ch, CURLINFO_HEADER_SIZE);
$header = substr($response, 0, $header_size);
$body = substr($response, $header_size);